Formation of stereocomplex crystals (SC) is an effective way to improve the heat resistance and mechanical performance of poly(lactic acid) products. However, at all but the slowest cooling rates, SC crystallization of a high-molecular-weight poly(L-lactic acid)/poly(D-lactic acid) (PLLA/PDLA) racemate stops at a hi...

https://pubs.acs.org/doi/10.1021/acs.macromol.2c02067